OXIDATION OF BENZENE TO PHENOL BY DINITROGEN MONOXIDE OVER FE-CONTAINING ZSM-5 ZEOLITES

Authors
SHEVELEVA GA KHARITONOV AS PANOV GI SOBOLEV VI RAZDOBAROVA NL PAUKSHTIS YA ROMANNIKOV VN
Citation
Ga. Sheveleva et al., OXIDATION OF BENZENE TO PHENOL BY DINITROGEN MONOXIDE OVER FE-CONTAINING ZSM-5 ZEOLITES, Petroleum chemistry, 33(6), 1993, pp. 516-524
Citations number
22
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
33
Issue
6
Year of publication
1993
Pages
516 - 524
Database
ISI
SICI code
0965-5441(1993)33:6<516:OOBTPB>2.0.ZU;2-P
Abstract
The oxidation of benzene to phenol by nitrogen(I) oxide is a recent ac hievement in the field of gas-phase catalysis. For the first time it w as shown to be possible to carry out this reaction over supported vana dium, molybdenum and tungsten oxides [1]. Considerably better results were able to be obtained by using zeolite catalysts [2-4]. Interest in this reaction is particularly great because the introduction of a hyd roxyl group into an aromatic ring is a difficult problem in organic sy nthesis, and the hydroxylation of benzene by nitrous oxide is regarded as the simplest reaction of this type that can be transferred to more complex aromatic compounds.