J. Morgado et al., ELECTRICAL-RESISTIVITY AND THERMOELECTRIC-POWER OF (TMTSF)2M(TDS)2, M=PT, CU AND NI - EVIDENCE FOR THE EXISTENCE OF 2 DIFFERENT PHASES, Solid state communications, 89(9), 1994, pp. 755-759
The electrical resistivity and thermoelectric power of (TMTSF)2M(tds)2
single crystals, M = Ni, Pt and Cu, were investigated in the range 20
- 300 K. These measurements show two distinct behaviours and provide
evidence for the existence of two different phases in the Pt and Ni co
mpounds. One, observed in plate shaped crystals, referred to as alpha-
phase, presents a 1st order transition, at ca. 275 and 245 K for the N
i and Pt compounds respectively, seen as an increase of conductivity a
nd decrease of thermopower. The other one, observed in thin needle cry
stals, referred to as beta-phase, has a clear metallic regime at high
temperature without such a 1st order transition. M = Cu crystals appea
r only as thin plates, with metallic properties at high temperature an
d without any 1st order transition. They present a different 2nd order
M-I transition at ca. 60 K with hysteresis in thermopower in the rang
e 60-120 K.