Cj. Brumlik et al., TEMPLATE SYNTHESIS OF METAL MICROTUBULE ENSEMBLES UTILIZING CHEMICAL,ELECTROCHEMICAL, AND VACUUM DEPOSITION TECHNIQUES, Journal of materials research, 9(5), 1994, pp. 1174-1183
Microtubules are an interesting type of microstructure that resemble m
iniature drinking straws. Such tubular microstructures are found in na
ture. In addition, we and others have been investigating strategies fo
r making synthetic analogs. We are especially interested in the idea o
f making metal microtubules. Four procedures for preparing metal micro
tubules are described in this paper. The general approach, called temp
late-synthesis, entails using the pores in a microporous membrane as t
emplates for forming the tubules. Microporous anodic aluminum oxide me
mbranes and nuclear track-etch membranes are used as the template memb
ranes. Gold and silver microtubules are made with outer diameters as s
mall as 200 nm. These microstructures are characterized by scanning el
ectron microscopy.