A NEW FAMILY OF LIGATED ANIONIC INITIATORS FOR THE LIVING POLYMERIZATION OF (METH)ACRYLIC ESTERS

Authors
BAYARD P JEROME R TEYSSIE P VARSHNEY S WANG JS
Citation
P. Bayard et al., A NEW FAMILY OF LIGATED ANIONIC INITIATORS FOR THE LIVING POLYMERIZATION OF (METH)ACRYLIC ESTERS, Polymer bulletin, 32(4), 1994, pp. 381-385
Citations number
14
Categorie Soggetti
Polymer Sciences
Journal title
Polymer bulletin → ACNP
ISSN journal
01700839
Volume
32
Issue
4
Year of publication
1994
Pages
381 - 385
Database
ISI
SICI code
0170-0839(1994)32:4<381:ANFOLA>2.0.ZU;2-G
Abstract
A new family of ligands (dual sigma - pi ligand), i.e. chelating lithi um alkoxides, Li-O-(CH2-CH2O)nCH3, is shown to be very effective in pr omoting the living anionic Polymerization of methacrylic and acrylic e sters, including a number of primary alkyl acrylates such as n-butyl a crylate and 2-ethylhexylacrylate.