ELECTRIC POLARIZATION OF ONSAGER FLUIDS .1. DIPOLE POLARIZATION .2. BINARY-SOLUTIONS OF ORGANIC-COMPOUNDS

Citation
Vv. Prezhdo et al., ELECTRIC POLARIZATION OF ONSAGER FLUIDS .1. DIPOLE POLARIZATION .2. BINARY-SOLUTIONS OF ORGANIC-COMPOUNDS, Acta Physica Polonica. A, 85(3), 1994, pp. 509-515
Citations number
10
Categorie Soggetti
Physics
Journal title
ISSN journal
05874246
Volume
85
Issue
3
Year of publication
1994
Pages
509 - 515
Database
ISI
SICI code
0587-4246(1994)85:3<509:EPOOF.>2.0.ZU;2-U
Abstract
Set forth in the previous report [1], the continual theory of dipole p olarization of molecular fluids, which suggests substitution of the ri gid Onsager sphere for the polarizable body and takes into considerati on electric induction of this body and its nearest surroundings, is ex tended in this-paper to binary solutions with diverse polarities. Dipo le moments of free molecules of dissolved substances were calculated f rom experimental data of dielectrometry of a large number of extremely diluted organic substances and are close to the corresponding gaseous phase values. On the ground of solution polarization measurements the criterion of physical consistency of various models of the condensed medium internal field is proposed.