The concave surface of mechanochemically treated Si(111) samples break
s up, under UHV treatment, into a large number of vicinal Si(111) surf
aces. The concave surface presents a continuous range of polar angles
up to 10-degrees for arbitrary azimuthal direction. Scanning tunneling
microscopy (STM) measurements, performed on different parts of the su
rface, have shown facetting into (111)-oriented, 7 X 7 reconstructed t
erraces, steps or step bunches. Characteristic step arrangements known
from individually prepared vicinal Si(111) surfaces have been identif
ied. On step bunches ordered regions with orientations corresponding t
o high-index (hkl) values have been observed. One of these could be as
signed to a (9 13 7) facet and is decribed in the present work.