A. Bilic et al., CONSTRUCTIVE INTERFERENCE EFFECTS IN ENERGY-LOSS SPECTRA OF ENERGETICNOBLE-GAS IONS AND ATOMS INCIDENT AT GLANCING INCIDENCE TO METAL-SURFACES, Surface science, 309, 1994, pp. 165-171
Scattering Of energetic noble gas ions and atoms at grazing incidence
from smooth (111) surfaces of metals (Cu, Al) produces energy loss dis
tributions with a no-loss contribution of low intensity (small Debye-W
aller factor) and a broad inelastic sideband. At keV beam energies, th
is sideband is typically peaked at a few to several tens of eV below t
he no-loss contribution. We propose that electronic excitations in the
metal are responsible for dissipation of the scattered particle kinet
ic energy, and argue that the observed magnitude can only be explained
by assuming a fluctuating effective charge or dipole on the moving pa
rticle. Constructive interference between successive fluctuation steps
gives rise to a high probability of translational energy loss and lea
ds to the experimentally observed shape of the loss spectra.