Since the origin of surface science noble metal/elemental semiconducto
r couples have been considered as ''prototypical'' systems. After thre
e decades of research their structural and electronic properties remai
n an intriguing maze despite recent advances made, especially thanks t
o the development of the near-field microscopies and the ''tensive use
of synchrotron radiation in surface crystallography and in high-resol
ution photoelectron spectroscopy. In the last few years, lead, as a re
placement inert metal, has nearly gained the pole position in the disp
lay of exotic behaviour. This paper gives a flavour of this mystery st
ory and highlights some puzzling questions.