SWELLING OF A LYOTROPIC HEXAGONAL PHASE BY MONITORING THE RADIUS OF THE CYLINDERS

Authors
Citation
L. Ramos et P. Fabre, SWELLING OF A LYOTROPIC HEXAGONAL PHASE BY MONITORING THE RADIUS OF THE CYLINDERS, Langmuir, 13(4), 1997, pp. 682-686
Citations number
19
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
07437463
Volume
13
Issue
4
Year of publication
1997
Pages
682 - 686
Database
ISI
SICI code
0743-7463(1997)13:4<682:SOALHP>2.0.ZU;2-R
Abstract
We report the elaboration of a lyotropic hexagonal mesophase with a ve ry large lattice parameter. The quaternary system studied displays a h exagonal phase of direct type, namely, nonpolar tubes in a polar mediu m: by varying the ionic force of the polar medium, i.e., by addition o f salt, we show that it is possible to realize hexagonal mesophases wi th swollen cylinders of monitored radius up to 17 nm. Moreover, from m icroscopic observations we have access to the elastic characteristics of the swollen lyotropic hexagonal phases, quantified by a penetration length lambda. We find that lambda increases with the swelling ratio and interpret this result via microscopic models.