PHONON-INDUCED SCATTERING BETWEEN VIBRATIONS AND MULTIPHOTON VIBRATIONAL UP-PUMPING IN LIQUID SOLUTION

Citation
A. Tokmakoff et al., PHONON-INDUCED SCATTERING BETWEEN VIBRATIONS AND MULTIPHOTON VIBRATIONAL UP-PUMPING IN LIQUID SOLUTION, Chemical physics letters, 221(5-6), 1994, pp. 412-418
Citations number
29
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
221
Issue
5-6
Year of publication
1994
Pages
412 - 418
Database
ISI
SICI code
0009-2614(1994)221:5-6<412:PSBVAM>2.0.ZU;2-0
Abstract
Fast phonon-induced scattering between an infrared active and a Raman active vibration in solution is investigated using picosecond infrared pump/anti-Stokes Raman probe experiments. Population from the infrare d active T1u CO stretching mode of tungsten hexacarbonyl in carbon tet rachloride at 1980 cm-1 scatters to the Raman active E(g) mode at 2012 cm-1 but not to the A1g mode at 2116 cm-1. Equilibration occurs rapid ly compared to the 700 ps population relaxation time. A power dependen ce of the line shape of the Raman mode indicates that significant popu lation is pumped into high vibrational levels when high infrared pump powers are used.