COMPARISON OF STRUCTURE-THERMAL PROPERTY RELATIONSHIPS FOR BARIUM BIS(1,1,1,5,5,5-HEXAFLUORO-2,4-PENTANEDIONATE POLYETHER COMPLEXES

Authors
INEROWICZ HD CHANDRASEKHAR TM ATKINSON G WHITE RL
Citation
Hd. Inerowicz et al., COMPARISON OF STRUCTURE-THERMAL PROPERTY RELATIONSHIPS FOR BARIUM BIS(1,1,1,5,5,5-HEXAFLUORO-2,4-PENTANEDIONATE POLYETHER COMPLEXES, Analytica chimica acta, 289(2), 1994, pp. 249-257
Citations number
48
Categorie Soggetti
Chemistry Analytical
Journal title
Analytica chimica acta → ACNP
ISSN journal
00032670
Volume
289
Issue
2
Year of publication
1994
Pages
249 - 257
Database
ISI
SICI code
0003-2670(1994)289:2<249:COSPRF>2.0.ZU;2-8
Abstract
The thermal properties of Ba(hfa)(2), Ba(hfa)(2)(tetraglyme), Ba(hfa)( 2)(18-crown-6), and Ba(hfa)(2)(diaza-18-crown-6) are investigated by c omparing the results of thermogravimetric analysis (TGA) for these mat erials. All TGA measurements were made in helium at atmospheric pressu re. Infrared, MS, NMR, and x-ray crystallographic measurements are com pared for each of the complexes and correlations are made between the structure-specific information derived from these analyses and the the rmal properties of the barium complexes.