SCATTERING OF NE FROM THE LIQUID-VAPOR INTERFACE OF GLYCEROL - A MOLECULAR-DYNAMICS STUDY

A model potential for the scattering of Ne off liquid glycerol is deve loped. The model is based on a nine-site description of glycerol which takes into account torsional flexibility and hydrogen bonding. This m odel is used to carry out molecular dynamics calculations of the scatt ering as a function of collision energy. The results for the sticking probability and energy transfer are in good agreement with experiments . The model predicts a wide angular distribution of the scattered atom s with a mild decrease in the energy transfer as a function of exit an gle for a fixed incident angle. The model also provides insight into t he importance of the corrugated nature of the surface and the types of liquid modes that play a major role in the energy transfer process.