We have successfully nickel doped a boron carbide (BSC) alloy film. Th
e nickel doped boron-carbide (Ni-B5C1+delta) thin films were fabricate
d from a single source carborane cage molecule and nickelocene [Ni(C5H
5)(2)] using plasma enhanced chemical vapor deposition, Nickel doping
transforms the highly resistive undoped film from ap-type material to
an n-type material. This has been verified from the characteristics of
diodes constructed of Ni-B5C1+delta a on both n-type silicon and p-ty
pe B5C. The homojunction diodes exhibit excellent rectifying propertie
s over a wide range of temperatures. (C) 1997 American Institute of Ph
ysics.