In the system of electrolyte (hydrofluoric acid - HF-48 %)-silicon (ph
osphorus doped, specific resistivity is equal to 4.5 OMEGA.cm) the sel
f-organization phenomena were discovered and investigated which are de
veloped during the pores formation and show themselves in formation of
periodic concentric structures of closepacked array of pores of two k
inds: circular and radial. Experimentally obtained current-potential c
haracteristic is S-formed. The surface of porous silicon, which was fo
rmed by different conditions, is investigated.