FACTORS AFFECTING THE CARBONYL STRETCHING FREQUENCIES OF DIALKYL KETONES AND ALKYL ALKANOATES IN VARIOUS SOLVENT SYSTEMS

Authors
NYQUIST RA
Citation
Ra. Nyquist, FACTORS AFFECTING THE CARBONYL STRETCHING FREQUENCIES OF DIALKYL KETONES AND ALKYL ALKANOATES IN VARIOUS SOLVENT SYSTEMS, Vibrational spectroscopy, 7(1), 1994, pp. 1-29
Citations number
8
Categorie Soggetti
Spectroscopy,"Chemistry Analytical","Chemistry Physical
Journal title
Vibrational spectroscopy → ACNP
ISSN journal
09242031
Volume
7
Issue
1
Year of publication
1994
Pages
1 - 29
Database
ISI
SICI code
0924-2031(1994)7:1<1:FATCSF>2.0.ZU;2-R
Abstract
The frequency behavior of the carbonyl stretching vibration, nu(C=O), is explained in terms of the reaction field, steric effects, inductive effects, and intermolecular hydrogen bonding. Our present study of di alkyl ketones and alkyl alkanoates in a variety of solvents was undert aken to obtain additional information on solute-solvent interaction as an aid in the elucidation of molecular structure.