IRON(II) AND MANGANESE(I) COMPLEXES CONTAINING DIPHOSPHINE LIGANDS - AN INFRARED STUDY OF BRMN(CO)2(DPPM)P(OPH)3 AND CPFE(DPPE)R (R=I, CN)

Authors
CAMPOS MM DIAZ C FIGUEROA K PADILLA L LARA N DIAZ G
Citation
Mm. Campos et al., IRON(II) AND MANGANESE(I) COMPLEXES CONTAINING DIPHOSPHINE LIGANDS - AN INFRARED STUDY OF BRMN(CO)2(DPPM)P(OPH)3 AND CPFE(DPPE)R (R=I, CN), Vibrational spectroscopy, 7(1), 1994, pp. 61-72
Citations number
54
Categorie Soggetti
Spectroscopy,"Chemistry Analytical","Chemistry Physical
Journal title
Vibrational spectroscopy → ACNP
ISSN journal
09242031
Volume
7
Issue
1
Year of publication
1994
Pages
61 - 72
Database
ISI
SICI code
0924-2031(1994)7:1<61:IAMCCD>2.0.ZU;2-E
Abstract
Infrared spectra in the region 4000-70 cm-1 are recorded for osphino)m ethane](triphenylphosphite)bromo(cis,cis- and trans-dicarbonyl)mangane se, and enyl-[1,2-bis(diphenylphosphino)ethane]iron(cyano) and -iodo c omplexes. Particular emphasis is given to the assignment of the metal- ligand bands, for which a normal coordinate analysis based on a simpli fied molecular model is performed. Effect of the isomerization and lig and substitution on the structure, stability and reactivity of all the complexes is also discussed.