Time-resolved spectra of Io have been obtained with the Faint Object S
pectrograph on the Hubble Space Telescope in January 1992 at times cen
tered on the passage of Io into Jupiter's shadow. Two different eclips
e observations covered 1100-1600 angstrom and 2250-3.300 angstrom. In
the far-UV range, emission lines of atomic sulfur and oxygen from Io's
atmosphere (similar to those previously detected with IUE) have been
observed from lo in sunlight, and the spatial extent of the emitting r
egion has been resolved for the first time: this is 0.5-1 Io radii (R(
Io)) above the surface. The emission lines are typically 1 kR in brigh
tness while lo is in sunlight, and decrease to a few hundred Rayleighs
within 20 min or less of Io's passing into shadow. If the emissions a
re produced in Io's ionosphere, the decrease in shadow appears consist
ent with the collisional slowing and recombination of photoelectrons i
n 100-1000 s, with recombination an important quenching process if the
dominant ion is molecular (i.e., SO2+). By contrast, the impact of co
rotating torus electrons is expected to continue when lo is in shadow.
If impact by torus plasma dominates the emission, the decrease in sha
dow may be due to surface SO2 condensation, with the residual emission
in shadow due either to plasma impact of gas above the hot volcanic c
alderas or electron impact on S and O. In the near-UV range, we have n
ot detected any airglow emissions from lo's atmosphere in shadow, with
the main limitation being a high level of scattered light from Jupite
r. We derive a 3sigma upper limit to the 2560 angstrom So emission fea
ture of 1 kR, which is close to what is expected from electron impact
on SO2 based on the observed brightness of the FUV S and O lines in sh
adow. A high signal-to-noise spectrum of Io's albedo in sunlight revea
ls a spectral shape similar to laboratory spectra of SO2 frost reflect
ivity, and the relative albedo spectrum changed as lo passed into ecli
pse and part of the disk was in shadow. No specific SO2 gas absorption
features appear in the albedo spectrum, although there could be subst
antial gas absorption near 2800 angstrom if the individual lines are n
arrow and saturated. Finally, we present preliminary models for the ne
ar-UV spectrum of Io as functions of SO2 frost areal coverage and SO2
gas density.