ELECTROCHEMISTRY OF ORGANOMETALLIC HALIDE-COMPLEXES .3. OXIDATION OF [C6ME6RUCL2]2

Authors
KOLLE U GORISSEN R HORNIG A
Citation
U. Kolle et al., ELECTROCHEMISTRY OF ORGANOMETALLIC HALIDE-COMPLEXES .3. OXIDATION OF [C6ME6RUCL2]2, Inorganica Chimica Acta, 218(1-2), 1994, pp. 33-39
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
218
Issue
1-2
Year of publication
1994
Pages
33 - 39
Database
ISI
SICI code
0020-1693(1994)218:1-2<33:EOOH.O>2.0.ZU;2-L
Abstract
The oxidative electrochemistry of [(HMB)RuCl2]2 (1) (HMB=eta6-C6Me6) r eveals the formation of an Ru(III) arene complex (HMB)RuCl3 (2). It is shown that the corresponding anion [(HMB)RuCl3]- (2-) is present in a n equilibrium in CH2Cl2 solution of 1. Complex 2 is prepared by chlori nation of 1 as the first arene complex of Ru(III).