SIMULTANEOUS BINDING OF SOFT AND HARD METALS TO A PYRIMIDINE NUCLEOBASE - TRANS-K2[PTI2(1-MEU)2].6H2O, AN ANIONIC PT-1-METHYLURACIL (1-MEU)COMPLEX ARRANGED IN CIRCLES

Authors
RENN O LIPPERT B MUTIKAINEN I
Citation
O. Renn et al., SIMULTANEOUS BINDING OF SOFT AND HARD METALS TO A PYRIMIDINE NUCLEOBASE - TRANS-K2[PTI2(1-MEU)2].6H2O, AN ANIONIC PT-1-METHYLURACIL (1-MEU)COMPLEX ARRANGED IN CIRCLES, Inorganica Chimica Acta, 218(1-2), 1994, pp. 117-120
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
218
Issue
1-2
Year of publication
1994
Pages
117 - 120
Database
ISI
SICI code
0020-1693(1994)218:1-2<117:SBOSAH>2.0.ZU;2-N
Abstract
The anionic complex trans-[PtI2(1-MeU-N3)2]2- (1-MeU=1-methyluracil an ion, C5H5N2O2), as its K salt, forms a supramolecular assembly with an ionic entities linked via K+ cations and bridging H2O molecules. The P t coordination sphere is normal square-planar. Crystallographic data a re as follows: C10H22I2K2N4O10Pt, rhombohedral, space group R3BAR, a=2 6.166(4), c=9.245(2) angstrom, U=5482(3) angstrom3, Z=9. The structure was refined to R=3.46, R(w)=4.63 for 1813 unique reflections with I>3 sigma(I).