CYCLOPALLADATED P-AZOXYANISOLE COMPLEXES - SYNTHESIS AND STRUCTURE OFOXYPHENYL-2-ATO]-PALLADIUM(II))(TETRAFLUOROBORATE)

Authors
ARMENTANO S DEMUNNO G GHEDINI M MORRONE S
Citation
S. Armentano et al., CYCLOPALLADATED P-AZOXYANISOLE COMPLEXES - SYNTHESIS AND STRUCTURE OFOXYPHENYL-2-ATO]-PALLADIUM(II))(TETRAFLUOROBORATE), Inorganica Chimica Acta, 218(1-2), 1994, pp. 211-213
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
218
Issue
1-2
Year of publication
1994
Pages
211 - 213
Database
ISI
SICI code
0020-1693(1994)218:1-2<211:CPC-SA>2.0.ZU;2-U
Abstract
Two molecules of Ph-Py (2-phenylpyridine) react with the solvate compl ex [(Azoxy-1)Pd(MeCN)2][BF4] to give the mononuclear cyclopalladated d erivative [(Azoxy-1)Pd(Ph-Py)2][BF4] (1). The X-ray crystal structure of complex 1 is reported. Crystals were triclinic P1BAR space group, w ith a=11.714(2), b=12.894(2), c=13.331(2) angstrom, beta=78.74(2), gam ma=6632(2)-degrees and Z=2. The structure was refined to R=0.054.