Ai. Fishman et Sf. Mironov, NEW POSSIBILITIES OF OVERLAPPING RAMAN BAND RESOLUTION BY METHODS OF CARS SPECTROSCOPY, Journal of Raman spectroscopy, 25(4), 1994, pp. 267-273
New possibilities for the resolution of Raman bands, provided by polar
ization-sensitive CARS in combination with a Phase-mismatching techniq
ue, are presented. The use of this combination of techniques allows on
e to achieve the most informative spectra and resolve the complex stru
cture of inhomogeneously broadened contours. The variation of the reso
nant/non-resonant ratio using a phase-mismatching technique and the sp
ecial possibilities of polarization CARS spectroscopy in lineshape for
mation are used. The results of an investigation of a cyclohexane and
naphthalene mixture and of n-pentane by polarization CARS in combinati
on with a phase-mismatching technique are presented.