TRANSITION-METAL SACCHARIDE CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF D-GLUCOSE, D-FRUCTOSE, D-GALACTOSE, D-XYLOSE, D-RIBOSE, AND MALTOSE COMPLEXES OF CO(II)

Authors
BANDWAR RP SASTRY MD KADAM RM RAO CP
Citation
Rp. Bandwar et al., TRANSITION-METAL SACCHARIDE CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF D-GLUCOSE, D-FRUCTOSE, D-GALACTOSE, D-XYLOSE, D-RIBOSE, AND MALTOSE COMPLEXES OF CO(II), Carbohydrate research, 297(4), 1997, pp. 333-339
Citations number
43
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Carbohydrate research → ACNP
ISSN journal
00086215
Volume
297
Issue
4
Year of publication
1997
Pages
333 - 339
Database
ISI
SICI code
0008-6215(1997)297:4<333:TSC-SA>2.0.ZU;2-9
Abstract
Monosaccharide (D-Glc, D-Fru, D-Gal, D-Xyl, and D-Rib) and disaccharid e (Mall complexes of Co(II) were synthesised from nonaqueous solutions using [NEt(4)](2)[CoCl2Br2] or CoCl2 . 6H(2)O and isolated in the sol id state. The purified complexes were characterized by diffuse reflect ance, aqueous solution absorbance, CD, FTIR, magnetic susceptibility, EPR, and cyclic voltammetric studies. The complexes synthesised from [ NEt(4)](2)[CoCl2Br2] were found to be primarily dinuclear, whereas tho se synthesised from CoCl2 . 6H(2)O were found to be di- or tetra-nucle ar. The hydrolytic stability of the complexes followed a trend: D-Rib > Mal > D-Glc > D-Xyl > D-Fru much greater than D-Gal. (C) 1997 Elsevi er Science Ltd.