TRANSITION-METAL SACCHARIDE CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF D-GLUCOSE, D-FRUCTOSE, D-GALACTOSE, D-XYLOSE, D-RIBOSE, AND MALTOSE COMPLEXES OF NI(II)

Authors
BANDWAR RP RAO CP
Citation
Rp. Bandwar et Cp. Rao, TRANSITION-METAL SACCHARIDE CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF D-GLUCOSE, D-FRUCTOSE, D-GALACTOSE, D-XYLOSE, D-RIBOSE, AND MALTOSE COMPLEXES OF NI(II), Carbohydrate research, 297(4), 1997, pp. 341-346
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Carbohydrate research → ACNP
ISSN journal
00086215
Volume
297
Issue
4
Year of publication
1997
Pages
341 - 346
Database
ISI
SICI code
0008-6215(1997)297:4<341:TSC-SA>2.0.ZU;2-8
Abstract
Monosaccharide (D-Glc, D-Fru, D-Gal, D-Xyl, D-Rib) and disaccharide (M al) complexes of Ni(II) were synthesised using [NEt(4)](2)[NiCl2Br2] o r NiCl2 . 6H(2)O in nonaqueous medium. The compounds synthesised from these two starting materials are different. The isolated complexes wer e characterized by diffuse reflectance, aqueous solution absorbance, C D, FTIR, magnetic susceptibility, and EXAFS and XANES studies. (C) 199 7 Elsevier Science Ltd.