It has been shown that, after a partial deactivation, gamma-alumina (g
amma-Al2O3) is a good catalyst for selective methylation of 1,2-benzen
ediol in the temperature range of 260 - 310-degrees-C. The main produc
ts are the desired 3-methyl-1,2-benzenediol and 2-methoxyphenol, which
may be converted in another step into 3-methyl-1,2-benzenediol, givin
g an overall selectivity for the desired products of 80 to 90%. The ca
techol forms a strongly chemisorbed surface species on gamma-alumina a
nd its steric adsorption model correlates with the kinetic data.