RHODIUM-CATALYZED HYDROAMINATION-HYDROARYLATION OF NORBORNENE WITH ANILINE, TOLUIDINES OR DIPHENYLAMINE

Authors
BRUNET JJ COMMENGES G NEIBECKER D PHILIPPOT K
Citation
Jj. Brunet et al., RHODIUM-CATALYZED HYDROAMINATION-HYDROARYLATION OF NORBORNENE WITH ANILINE, TOLUIDINES OR DIPHENYLAMINE, Journal of organometallic chemistry, 469(2), 1994, pp. 221-228
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
469
Issue
2
Year of publication
1994
Pages
221 - 228
Database
ISI
SICI code
0022-328X(1994)469:2<221:RHONWA>2.0.ZU;2-W
Abstract
The condensation of aniline, toluidines or diphenylamine with norborne ne tetrahydrofuran is promoted by a system generated from Li(n)Bu, ArN H2 and [{(PEt3)2RhCl}2]. Aniline and m- and p-toluidines lead to a mix ture of hydroamination and hydroarylation products whereas o-toluidine and diphenylamine lead to the hydroarylation product only. When condu cted in the amine as solvent, the reaction is catalytic with respect t o both lithium and rhodium.