CONFORMATIONAL EQUILIBRIUM IN TRANS,TRANS,TRANS-CYCLODODECATRIENE (CDT) - STUDIES ON -DICHLORO(CDT)ALPHA-METHYLBENZYLAMINE-PLATINUM(II)

Authors
PAIARO G GANIS P
Citation
G. Paiaro et P. Ganis, CONFORMATIONAL EQUILIBRIUM IN TRANS,TRANS,TRANS-CYCLODODECATRIENE (CDT) - STUDIES ON -DICHLORO(CDT)ALPHA-METHYLBENZYLAMINE-PLATINUM(II), Journal of organometallic chemistry, 469(2), 1994, pp. 30000034-30000036
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
469
Issue
2
Year of publication
1994
Pages
30000034 - 30000036
Database
ISI
SICI code
0022-328X(1994)469:2<30000034:CEIT(>2.0.ZU;2-D
Abstract
A pure diastereoisomer of the complex trans-[Pt(CDT)Cl2{(R)-alpha-meth ylbenzylamine} has been isolated. Circular dichroism and polarimetric measurements revealed the non-equivalence of the three diastereotopic olefin residues in the coordinated cycloolefin. This indicated a confo rmational equilibrium D3 half arrow right over half arrow left C1, whi ch has been explained in terms of stereochemical and thermodynamic con siderations.