BETA-DIKETONATE AND ALPHA,BETA-UNSATURATED-BETA-KETOAMINATE COMPLEXESOF RUTHENIUM(II) CONTAINING CARBONYL, THIOCARBONYL AND PYRIDINE LIGANDS

Authors
MUTHUSAMY G RAMESH R NATARAJAN K
Citation
G. Muthusamy et al., BETA-DIKETONATE AND ALPHA,BETA-UNSATURATED-BETA-KETOAMINATE COMPLEXESOF RUTHENIUM(II) CONTAINING CARBONYL, THIOCARBONYL AND PYRIDINE LIGANDS, Synthesis and reactivity in inorganic and metal-organic chemistry, 24(4), 1994, pp. 545-560
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
24
Issue
4
Year of publication
1994
Pages
545 - 560
Database
ISI
SICI code
0094-5714(1994)24:4<545:BAAC>2.0.ZU;2-S
Abstract
Hexacoordinated ruthenium(II) complexes of the types [RuCl(CO)(Py)(PPh 3)(betadk)], [RuCl(CS)(py)(PPh3)(betadk)], [RuCl(CO)(Py)(PPh3)(LL')] a nd [RuCl(CS)(py)(PPh3)(LL')] (where Py = pyridine, betadk = beta-diket onate and LL' = alpha,beta-unsaturated-beta-ketoaminate) have been pre pared by the reactions of [RuHCl(CO)(Py)(PPh3)2] and [RuCl2(CS)(Py)(PP h3)2] with beta-diketones and alpha,beta-unsaturated-beta-ketoamines. The complexes were characterised by means of analytical and spectral d ata (IR, electronic, H-1 and P-31 NMR).