TRIPHENYLPHOSPHINE AND TRIPHENYLARSINE COMPLEXES OF RUTHENIUM(III) CONTAINING DITHIOCARBAZATE SCHIFF-BASES

Authors
CHINNUSAMY V MUTHUSAMY G NATARAJAN K
Citation
V. Chinnusamy et al., TRIPHENYLPHOSPHINE AND TRIPHENYLARSINE COMPLEXES OF RUTHENIUM(III) CONTAINING DITHIOCARBAZATE SCHIFF-BASES, Synthesis and reactivity in inorganic and metal-organic chemistry, 24(4), 1994, pp. 561-574
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis and reactivity in inorganic and metal-organic chemistry → ACNP
ISSN journal
00945714
Volume
24
Issue
4
Year of publication
1994
Pages
561 - 574
Database
ISI
SICI code
0094-5714(1994)24:4<561:TATCOR>2.0.ZU;2-W
Abstract
Several new hexacoordinated ruthenium(III) complexes of the type [RuX2 (LL)(EPh3)2] (where X = Cl or Br; E = P or As and LL = S-benzyldithioc arbazate or S-methyldithiocarbazate) have been synthesised. The Schiff bases deprotonate and behave as uninegative bidentate nitrogen sulphu r (NS-) chelating ligands. All the new complexes have been characteris ed on the basis of their analytical, IR, EPR and electronic spectrosco pic data.