H. Otsuka et al., ALANGIONOSIDE-A AND ALANGIONOSIDE-B, IONOL GLYCOSIDES FROM LEAVES OF ALANGIUM-PREMNIFOLIUM, Phytochemistry, 35(5), 1994, pp. 1331-1334
From leaves of Alangium premnifolium harvested on Okinawa island, two
new ionol glycosides, named alangionodises A and B, along with dendran
themoside A and benzyl alcohol xyloglucoside, were isolated. Their str
uctures were determined mainly by means of spectroscopic methods. The
application of beta-D-glucosylation induced shift trends for the deter
mination of the absolute configuration of a carbon atom having a secon
dary hydroxyl group is also discussed.