A colloidal crystalline dispersion of monodisperse silica spheres in m
ethyl methacrylate (MMA) photopolymerizes to a PMMA film. The composit
e film retains the fcc order of the monomer dispersion and is a select
ive filter of visible light at 490 nm by Bragg diffraction. A d111 sur
face layer of the composite is shown in the SEM.