A PRONOUNCED AXIAL LIGAND EFFECT ON THE REACTIVITY OF OXOIRON(IV) PORPHYRIN CATION RADICALS

Authors
GROSS Z NIMRI S
Citation
Z. Gross et S. Nimri, A PRONOUNCED AXIAL LIGAND EFFECT ON THE REACTIVITY OF OXOIRON(IV) PORPHYRIN CATION RADICALS, Inorganic chemistry, 33(9), 1994, pp. 1731-1732
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
33
Issue
9
Year of publication
1994
Pages
1731 - 1732
Database
ISI
SICI code
0020-1669(1994)33:9<1731:APALEO>2.0.ZU;2-T
Abstract
The rate constants for the epoxidation of styrene by six oxoiron(IV) p orphyrin cation radicals 1-X (X = -F, HOCH3, -Cl, -OAc, -OSO2CF3, -OCl O3) which differ only in the identity of their axial ligan were obtain ed under conditions where the presence of the axial ligands during the reactions could be ascertained. A qualitative relationship was found between the field strengths of the ligands and their pronounced effect on the reactivity of 1-X.