PALLADIUM COMPLEXES WITH THE TRIDENTATE DIANIONIC LIGAND PYRIDINE-2,6-BIS(THIOCARBOXYLATE), PDTC - CRYSTAL-STRUCTURE OF (N-BU4N)[PD(PDTC)BR]

Authors
ESPINET P LORENZO C MIGUEL JA BOIS C JEANNIN Y
Citation
P. Espinet et al., PALLADIUM COMPLEXES WITH THE TRIDENTATE DIANIONIC LIGAND PYRIDINE-2,6-BIS(THIOCARBOXYLATE), PDTC - CRYSTAL-STRUCTURE OF (N-BU4N)[PD(PDTC)BR], Inorganic chemistry, 33(9), 1994, pp. 2052-2055
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
33
Issue
9
Year of publication
1994
Pages
2052 - 2055
Database
ISI
SICI code
0020-1669(1994)33:9<2052:PCWTTD>2.0.ZU;2-M
Abstract
The reaction of [Pd(acac)2] with pyridine-2,6-bis-(thiocarboxylic) aci d (H-2pdtc) in chloroform affords [Pd(pdtc)]2, which has been used as starting material in the preparation of a variety of neutral and anion ic complexes [Pd(pdtc)L]0,- containing the planar tridentate ligand pd tc. The X-ray structure of (n-Bu4N)[Pd(pdtc)Br] shows the pdtc dianion as a S,N,S-tridentate chelate ligand forming two strain-free palladac ycles.