SPECTROSCOPIC AND STRUCTURAL CHARACTERIZATION OF DIPHOSPHINE AND DIARSINE COMPLEXES OF IRON(III) IODIDE

Authors
CHAMPNESS NR LEVASON W OLDROYD RD PREECE SR
Citation
Nr. Champness et al., SPECTROSCOPIC AND STRUCTURAL CHARACTERIZATION OF DIPHOSPHINE AND DIARSINE COMPLEXES OF IRON(III) IODIDE, Inorganic chemistry, 33(9), 1994, pp. 2060-2061
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
33
Issue
9
Year of publication
1994
Pages
2060 - 2061
Database
ISI
SICI code
0020-1669(1994)33:9<2060:SASCOD>2.0.ZU;2-A
Abstract
The first examples of pseudooctahedral iron(III) iodide complexes, tra ns-[Fe(L-L)212]BF4 (L-L = o-C6H4(PMe2)2, o-C6H4(AsMe2)2, o-C6F4(AsMe2) 2), have been isolated and characterized by cyclic voltammetry, UV-vis ible spectroscopy, and the first coordination sphere bond lengths esta blished by Fe K-edge EXAFS.