Surface steps act as confining barriers for electrons in metal-surface
states. Thus, narrow terraces and small single-atom-high metal island
s act as low-dimensional, electron-confining structures. In sufficient
ly small structures, quantum-size effects are observable even at room
temperature. Scanning tunneling spectroscopy is used to image the prob
ability amplitude distributions and discrete spectra of the confined s
tates. Examination of the electronic structure of the steps provides e
vidence for electron-density smoothing and the formation of step-edge
states. Estimates of the electron-confining barriers are obtained.