We propose a complementary pressure swing adsorption (CPSA) process co
nsisting of four beds for separating air into enriched oxygen and nitr
ogen. Simulation results showed that the CPSA process performed better
than either the oxygen process or the nitrogen process. Using zeolite
5A and 4A as adsorbents, the mole fraction of oxygen and argon in the
enriched oxygen may be as high as 99.57% (at 34.44% recovery), and th
e purity of the enriched nitrogen about 98% (at 47.86% recovery). For
producing enriched oxygen of 80-90% purity, a modified CPSA process is
suggested. The relationships between production rate, purity, and oxy
gen and nitrogen recoveries are discussed