HETEROLYTIC C,O-BOND CLEAVAGE OF 4'-NUCLEOTIDE RADICALS

Authors
GIESE B ERDMANN P GIRAUD L GOBEL T PETRETTA M SCHAFER T VONRAUMER M
Citation
B. Giese et al., HETEROLYTIC C,O-BOND CLEAVAGE OF 4'-NUCLEOTIDE RADICALS, Tetrahedron letters, 35(17), 1994, pp. 2683-2686
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
17
Year of publication
1994
Pages
2683 - 2686
Database
ISI
SICI code
0040-4039(1994)35:17<2683:HCCO4R>2.0.ZU;2-G
Abstract
Photolysis of selenoacetals 7-10 and acylselenides 13 and 14 generates 4'-deoxyribonucleotide radicals. Photocurrent experiments show that r adicals with a phosphate group in beta-position give rise to a heterol ytical bond cleavage.