ENEHYDROXYLAMINES AS VERSATILE COMPOUNDS IN 3,3-SIGMATROPIC REARRANGEMENTS

Authors
REIS LV LOBO AM PRABHAKAR S
Citation
Lv. Reis et al., ENEHYDROXYLAMINES AS VERSATILE COMPOUNDS IN 3,3-SIGMATROPIC REARRANGEMENTS, Tetrahedron letters, 35(17), 1994, pp. 2747-2750
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
17
Year of publication
1994
Pages
2747 - 2750
Database
ISI
SICI code
0040-4039(1994)35:17<2747:EAVCI3>2.0.ZU;2-X
Abstract
Enehydroxylamines react readily, in the presence of base, with electro philes containing unsaturation to afford intermediates that, either sp ontaneously or upon heating, lead via a 3,3-sigmatropic rearrangement to alpha-substituted products.