RADIOCHEMICAL PROCESSES IN THE POLYCARBONATE POLYBUTYLENETEREPHTHALATE SYSTEM

Authors
ORLOV AY FELDMAN VI SUKHOV FF
Citation
Ay. Orlov et al., RADIOCHEMICAL PROCESSES IN THE POLYCARBONATE POLYBUTYLENETEREPHTHALATE SYSTEM, High energy chemistry, 27(6), 1993, pp. 438-444
Citations number
12
Categorie Soggetti
Chemistry Physical
Journal title
High energy chemistry → ACNP
ISSN journal
00181439
Volume
27
Issue
6
Year of publication
1993
Pages
438 - 444
Database
ISI
SICI code
0018-1439(1993)27:6<438:RPITPP>2.0.ZU;2-T
Abstract
Low-temperature IR spectroscopy is used to study the radiolytic format ion of CO2 and CO in polycarbonate, polybutyleneterephthalate, and mix tures with various mixing times. Mixing the homopolymers is shown to a ffect the spectroscopic characteristics of the CO2 and CO bands. The f ormation of CO is modeled as a stabilization of part of the CO molecul e near radiation defects (primarily negative ions).