In photon beam convolution calculations where polyenergetic energy dep
osition kernels (EDKS) are used, the primary photon energy spectrum sh
ould be correctly accounted for in Monte Carlo generation of EDKS. Thi
s requires the probability of interaction, determined by the linear at
tenuation coefficient, mu, to be taken into account when primary photo
n interactions are forced to occur at the EDK origin. The use of prima
ry and scattered EDKS generated with a fixed photon spectrum can give
rise to an error in the dose calculation due to neglecting the effects
of beam hardening with depth. The proportion of primary photon energy
that is transferred to secondary electrons increases with depth of in
teraction, due to the increase in the ratio mu(ab)/mu as the beam hard
ens. Convolution depth-dose curves calculated using polyenergetic EDKS
generated for the primary photon spectra which exist at depths of 0,
20 and 40 cm in water, show a fall-off which is too steep when compare
d with EGS4 Monte Carlo results. A beam hardening correction factor ap
plied to primary and scattered 0 cm EDKS, based on the ratio of kerma
to terma at each depth, gives primary, scattered and total dose in goo
d agreement with Monte Carlo results.