The recovery of Co(II) ions from aqueous solutions under acidic condit
ions (pH 5) was investigated in flotation columns with inside diameter
s of 4.0 and 8.0 cm. Three surfactants, dodecylamine, cetyl pyridinium
chloride, and sodium dodecyl sulfate, were used as collectors. Sodium
dodecyl sulfate was found to be the most efficient; all three, howeve
r, produced hydrated froths, leading to rather low recoveries and sepa
ration efficiencies. The volumetric ps flow rate was found to affect t
he process in relation to the amount of surfactant added and the colum
n diameter. The scale-up of the column should be done in terms of the
same superficial gas velocity in order to maintain similar levels of m
etal ion recovery.