Thermochemical treatment in a glow discharge is a new and effective su
rface hardening process. One version of this method, ion carburizing,
is acknowledged to be the method of choice for treatment of heavy-load
machine parts. Despite the practical use of ion carburizing, scientif
ic ideas concerning the interaction of the gaseous medium activated by
the glow discharge with the surface of the metal to be saturated have
not been adequately formulated. The characteristics of external mass
transport remain the least studied, due to the complexity and diversit
y of the physicochemical processes occurring both in a nonequilibrium
ionized atmosphere and on the surface to be saturated. This paper is d
evoted to the investigation of these characteristics, based on optical
spectral diagnostics of the glow discharge.