M. Fleischer et al., A SELECTIVE H-2 SENSOR IMPLEMENTED USING GA2O3 THIN-FILMS WHICH ARE COVERED WITH A GAS-FILTERING SIO2 LAYER, Sensors and actuators. B, Chemical, 36(1-3), 1996, pp. 297-302
N-type semiconducting Ga2O3 thin-films which are stable at high temper
atures are used as a new basic material for gas sensors. This study in
vestigates the extent to which a gas-filtering layer of compact, amorp
hous SiO2 is capable of modifying gas sensitivity. Using a sputtering
technique and a Si target, the SiO2 layer, which, typically, has thick
nesses of 30 nm and 300 nm, is deposited onto the Ga2O3 gas sensor. It
was found that sensors with this surface layer structure had an extre
mely high specificity for H-2 when they were operated at 700 degrees C
. Other gases that were tested included CO, CO2, CH4, isobutene, ethan
ol, acetone, NO, NH3; variations of humidity and oxygen content were a
lso investigated. There was a marked increase in H-2-sensitivity betwe
en the modified and unmodified sensors.