ON A NEW MECHANISM OF RADIATION-INDUCED CONDUCTIVITY IN POLYMERS WITHSTRONG DONOR-ACCEPTOR INTERACTION

Citation
Ap. Tyutnev et al., ON A NEW MECHANISM OF RADIATION-INDUCED CONDUCTIVITY IN POLYMERS WITHSTRONG DONOR-ACCEPTOR INTERACTION, High energy chemistry, 28(2), 1994, pp. 103-105
Citations number
11
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00181439
Volume
28
Issue
2
Year of publication
1994
Pages
103 - 105
Database
ISI
SICI code
0018-1439(1994)28:2<103:OANMOR>2.0.ZU;2-V
Abstract
The results of a study on electron-beam-induced conductivity in a comm ercial polyimide and Kapton N film (at a dose rate above 100 Gy/s) are reported. It is found that the radiation-induced conductivity (RC) is caused by both the free-ion generation mechanism and by the additiona l conductance component determined by the formation of the metastable microscopic inhomogeneous polyconjugated structures. It is observed th at the process is accompanied by the superlinear voltage-current chara cteristics both during and after irradiation, the strong RC dependence on the absorbed radiation dose, and other phenomena.