ELECTROCATALYSIS OF METALLOPORPHYRINS .14. ELECTROOXIDATION OF HYDRAZINE CATALYZED BY WATER-SOLUBLE TETRAKIS (4-TRIMETHYLAMMONIUMPHENYL) PORPHYRIN AND ITS COBALT COMPLEX

Authors
PANG DW DENG BH WANG ZL
Citation
Dw. Pang et al., ELECTROCATALYSIS OF METALLOPORPHYRINS .14. ELECTROOXIDATION OF HYDRAZINE CATALYZED BY WATER-SOLUBLE TETRAKIS (4-TRIMETHYLAMMONIUMPHENYL) PORPHYRIN AND ITS COBALT COMPLEX, Electrochimica acta, 39(6), 1994, pp. 847-851
Citations number
12
Categorie Soggetti
Electrochemistry
Journal title
Electrochimica acta → ACNP
ISSN journal
00134686
Volume
39
Issue
6
Year of publication
1994
Pages
847 - 851
Database
ISI
SICI code
0013-4686(1994)39:6<847:EOM.EO>2.0.ZU;2-C
Abstract
The catalytic electro-oxidation of hydrazine by H2TMAP and CoTMAP has been investigated. The kinetic parameters of the electrode reaction we re measured and the reaction mechanism for the electro-oxidation of hy drazine in the presence of H2TMAP and CoTMAP is proposed. The electroc atalysis of the porphyrin ring, a novel kind of electrocatalysis of me talloporphyrins, is discussed.