THE ASSIGNMENT OF THE RAMAN AND FAR-INFRARED SPECTRA OF PH3SNX (X=CL,BR, I) AND PH4SN - A REAFFIRMATION

Authors
WHARF I
Citation
I. Wharf, THE ASSIGNMENT OF THE RAMAN AND FAR-INFRARED SPECTRA OF PH3SNX (X=CL,BR, I) AND PH4SN - A REAFFIRMATION, Spectrochimica acta. Part A: Molecular spectroscopy, 50(5), 1994, pp. 903-907
Citations number
27
Categorie Soggetti
Spectroscopy
Journal title
Spectrochimica acta. Part A: Molecular spectroscopy → ACNP
ISSN journal
05848539
Volume
50
Issue
5
Year of publication
1994
Pages
903 - 907
Database
ISI
SICI code
0584-8539(1994)50:5<903:TAOTRA>2.0.ZU;2-8
Abstract
Complete solid state Raman (460-50 cm-1) and far-IR (460-100 cm-1) spe ctra are reported for Ph3SnX(X = Cl, Br, I) and Ph4Sn. The assignments reaffirm and clarify those given earlier, particularly for nu SnX and are consistent with all Ph3SnX being monomeric. Preliminary results f rom X-ray analysis show Ph3SnI is triclinic, space group P1BAR, with Z = 4. The Ph3SnI molecules have almost trigonal symmetry around the ti n while shortest intermolecular d(Sn---I) values are > 6.3 angstrom.