SURFACE-ENHANCED RAMAN-SPECTROSCOPY OF FREE BILIRUBIN AND BILIRUBIN COMPLEXES WITH TRANSITION-METALS IRON(II), NICKEL(II) AND COBALT(II)

Authors
CHEN J HU JM XU ZS SHENG RS
Citation
J. Chen et al., SURFACE-ENHANCED RAMAN-SPECTROSCOPY OF FREE BILIRUBIN AND BILIRUBIN COMPLEXES WITH TRANSITION-METALS IRON(II), NICKEL(II) AND COBALT(II), Spectrochimica acta. Part A: Molecular spectroscopy, 50(5), 1994, pp. 929-936
Citations number
19
Categorie Soggetti
Spectroscopy
Journal title
Spectrochimica acta. Part A: Molecular spectroscopy → ACNP
ISSN journal
05848539
Volume
50
Issue
5
Year of publication
1994
Pages
929 - 936
Database
ISI
SICI code
0584-8539(1994)50:5<929:SROFBA>2.0.ZU;2-4
Abstract
The surface-enhanced Raman scattering (SERS) spectra of free bilirubin and bilirubin complexes with transition metals [iron(II), nickel(II) and cobalt(II)] are investigated on colloidal silver. Free bilirubin i s found to be adsorbed on colloidal silver at the lactam and dicarboxy late oxygens. The addition of some transition metal ions results in ra pid, square planar complex formation and the complex ratio of bilirubi n with the metal ion is 1:1.