SYNTHESIS OF ALIPHATIC 1,2-BISHYDROXYLAMINES FROM 1,3-DIHYDROXYIMIDAZOLIDINES - THE CRYSTAL-STRUCTURE OF 1,2-BISHYDROXYLAMINOCYCLOALKANES

Authors
MAZHUKIN DG TIKHONOV AY VOLODARSKII LB KONOVALOVA EP TIKHONOVA LA BAGRYANSKAYA IY GATILOV YV
Citation
Dg. Mazhukin et al., SYNTHESIS OF ALIPHATIC 1,2-BISHYDROXYLAMINES FROM 1,3-DIHYDROXYIMIDAZOLIDINES - THE CRYSTAL-STRUCTURE OF 1,2-BISHYDROXYLAMINOCYCLOALKANES, Russian chemical bulletin, 42(5), 1993, pp. 851-857
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
5
Year of publication
1993
Pages
851 - 857
Database
ISI
SICI code
1066-5285(1993)42:5<851:SOA1F1>2.0.ZU;2-X
Abstract
Reduction of 1-hydroxy-3-imidazoline-3-oxides with NaBH4 gives 1,3-dih ydroxyimidazolidines. The latter on subsequent treatment with NH2OH.HC l in EtOH or in hydrochloric acid afford 1,2-bishydroxylamines. An X-r ay study of 1,2-bishydroxylaminocycloalkanes has shown them to be cis- configurated.