REACTION OF FURFURYLIDENE ACETONE WITH GRIGNARD-REAGENTS

Authors
POLIVIN YN KARAKHANOV RA KELAREV VI UGRAK BI PANINA ME
Citation
Yn. Polivin et al., REACTION OF FURFURYLIDENE ACETONE WITH GRIGNARD-REAGENTS, Russian chemical bulletin, 42(5), 1993, pp. 878-880
Citations number
4
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
5
Year of publication
1993
Pages
878 - 880
Database
ISI
SICI code
1066-5285(1993)42:5<878:ROFAWG>2.0.ZU;2-1
Abstract
The interaction of furfurylidene acetone with methylmagnesium iodide a nd ethylmagnesium halides has been studied. In the first case 2-methyl -4-(2-furyl)-3-buten-2-ol is formed as the product of 1,2-addition (yi eld 73 %). In the second case 4-(2-furyl)-2-hexanone (42 %) is the res ult of 1,4-addition, whereas 3-methyl-5-(2-furyl)-3-heptanol (45 %) is formed by consecutive 1,2- and 1,4-addition. In all cases the product s of 1,3-addition were found.