I. Ulkem et G. Akovali, MECHANICAL-PROPERTIES OF SURFACE-MODIFIED BAUXITE FILLED SBR VULCANIZATES .1., European Polymer Journal, 30(5), 1994, pp. 567-572
The ultimate properties of rubber products are strongly influenced by
the size, size distribution, structure, surface area and surface selec
tivity of fillers. In this study, natural bauxite was coated with plas
ma polymer (polystyrene or polybutadiene) to modify surface properties
. The coated and uncoated bauxites were tested as filler for SBR vulca
nizates, using static and dynamic mechanical methods. The fracture sur
faces of the vulcanizates were investigated by SEM. Plasma polymer mod
ified bauxite loaded materials showed appreciable changes in hardness
compared with samples loaded with uncoated bauxite. It was concluded t
hat surface selectivity plays a more important role than surface area
for bauxite in the SBR vulcanizates.