SYNTHESIS OF AMORPHOUS HIGHLY FLUORINATED POLYMERS AT HIGH TG - COPOLYMERIZATION OF FLUORINATED MALEIMIDES WITH VINYL ETHERS

Authors
BEAUNE O BESSIERE JM BOUTEVIN B ROBIN JJ
Citation
O. Beaune et al., SYNTHESIS OF AMORPHOUS HIGHLY FLUORINATED POLYMERS AT HIGH TG - COPOLYMERIZATION OF FLUORINATED MALEIMIDES WITH VINYL ETHERS, Journal of fluorine chemistry, 67(2), 1994, pp. 159-167
Citations number
42
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
67
Issue
2
Year of publication
1994
Pages
159 - 167
Database
ISI
SICI code
0022-1139(1994)67:2<159:SOAHFP>2.0.ZU;2-G
Abstract
We have prepared and characterized (by H-1 NMR and MS methods) N-4-(2' -F-hexylethoxy)phenylmaleimide and N-4-(2'-F-hexylethylthio)phenylmale imide. The behaviour of these fluorinated maleimides (FM) towards vari ous vinyl ethers (2-chloroethylvinyl ether, benzylvinyl ether) in radi cal copolymerization has been studied. Generally, maleimides and vinyl ethers lead to alternated copolymers but, in this case, the copolymer was not alternated. The thermal behaviour of the copolymers has been evaluated and their thermal decomposition explained.